Three‐dimensional representations of toxic effects are rare. Only concentration–time–response models can be readily derived from conventional test data. Functions of this sort can be derived from the data that are required from flow‐through 96‐hour LC50 tests of fish by ASTM and EPA protocols (ASTM 1991; USEPA 1982). Such models have the obvious advantage of allowing the assessor to estimate the level of effects from various combinations of exposure concentration and duration. The response surfaces developed by Richardson and Burton (1981) for two estuarine species exposed to ozonated water and for trees exposed to SO2 are good examples.

Concentration–time–response relationships can also be a useful tool for dealing with diverse data. If test data are diverse with respect to both duration and severity of effects, then both of these dimensions must be related to concentration if regulatory criterion concentrations are to be calculated. Dourson (1986) explained how this is done to estimate allowable daily intake for humans. The various exposures are categorized as having no observed effect, no observed adverse effect, adverse effects, or frank effects. This severity scale is then translated into a series of symbols that are plotted on a dose and time surface. Lines are then fitted by eye separating the categories of severity and establishing the no adverse effect level, adverse effect level, and frank effect level. The same approach has been used by the EPA to set air quality criteria for phytotoxic effects of air pollutants. The U.S. Department of Agriculture reported that ground‐level ozone causes more damage (growth and yield) to plants than other air pollutants combined (Figures 5.12 and 5.13a, b) (USDA 2011).

Having characterized the risk of exposure to chemical release to air, water, and land, and the degree of uncertainty associated with the risk, the next step is to use the information to improve the basis for making decisions. This often involves the public, or at least embrace public concerns and attitude. It requires an examination of the question, “what is acceptable risk?” An essential part of this is risk communication – communication in terms of openness and transparency, understanding and engaging stakeholders, as well as providing balanced information to allow public make decisions on how to deal with risk.

Plastic Waste Choking Oceans, Rivers, Landfills

About 60% of the 9.1 billion T of plastic produced throughout history has ended up as waste, with more than three‐fourths of that going into landfills or the natural environment. Only 14% of plastic packing is currently collected for recycling. Figure 5.14 shows some of the plastic waste that washed up at the site of the old Queenhithe dock on the River Thames in London (Seattle Times, 22 February 2018). It is estimated that in 2010 alone, between 4.4 million and 13.2 million T of plastic entered the marine environment. The report also highlighted that the weight of plastic in the ocean would equal that of fish by 2050 if current trend continue.

Graph of NO2 concentration ppm (v/v) versus duration of exposure (hours) displaying 4 descending curves labeled Death, Metabolic and growth, Effect, and Threshold for foliar lesions.
Figure 5.12 Categorization of effects of NO2 on plants arrayed with respect to concentrations and duration of exposure.Source: From USEPA (1982).

In an article published in The New York Times (23 March 2018a issue), it is reported that about 87 000 T of plastic are present in the Pacific Ocean region. In the Pacific Ocean between California and Hawaii, hundreds of miles from any major city, plastic bottles, children’s toys, broken electronics, abandoned fishing nets, and millions more fragments of debris are floating in the water. This notorious mess has become known as the Great Pacific Garbage Patch, a swirling oceanic graveyard where everyday objects get deposited by the currents. The plastic eventually disintegrate into tiny particles that are often eaten by fish and may ultimately enter our food chain (New York Times, 23 March 2018a).

According to these reports, Amcor, Ecover, Evian, L’Oreal, Mars, M&S, Pepsi Co, Coca‐Cola, Unilever, Walmart, and Warner & Mertz – which together use more than 6 million MT of plastic packing a year – has committed to use only reusable, recyclable, or compostable packing by 2025. Amid growing evidence of the risks posed by plastic waste worldwide, some companies are embracing conservation and more recycling (see RCRA in Section 4.20.7 on resource conservation and recovery and for more on plastic recycling in Section 4.20.6).

Graph of relative yield (%) versus seasonal mean ozone (ppb) displaying descending solid curves with various shades labeled Sorghum, Field com, Winter wheat, Soybean, Peanut, and Cotton, etc.
Figure 5.13 (a) Ozone damage to radish plant resulting in smaller radish. (b) Effects of ozone on plants’ growth and yield. Heck et al. (1983).Source: From Haggestad (2001).
Image described by caption.
Figure 5.14 Plastic waste in River Thames in London.

More than 48 lb of plastic, including disposable dishes, corrugated tubes, shopping bags, and a detergent package with its bard code still visible, were found inside a dead sperm whale (Figure 5.15). This was the latest in a grim international collection of whale carcasses burdened by dozens of pounds of plastics trash. Europe is the second largest plastics manufacturer in the world, dumping 150–500 thousand T of macroplastics and 70–130 thousand T of microplastics in the sea every year. “Plastic pollution is one of the worst enemies of marine species in the world today.”


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