CARBURIZING

Carburizing is a heat treatment process in which iron or steel absorbs carbon liberated when the metal is heated in the presence of a carbon-rich atmosphere, such as charcoal or carbon monoxide, with the intent of making the metal harder. Depending on the amount of time and temperature, the affected area can vary in carbon content. Longer carburizing times and higher temperatures lead to greater carbon diffusion into the part as well as increased depth of carbon diffusion. When the iron or steel is quenched, the higher carbon content on the outer surface becomes hard via the transformation from austenite to martensite, while the core remains soft and tough as a ferritic and/or pearlite microstructure. It is applied to low-carbon workpieces; workpieces are in contact with a high-carbon gas, liquid, or solid; it produces a hard workpiece surface; workpiece cores largely retain their toughness and ductility; and it produces case hardness depths of up to 6.4 mm.

Gas Carburizing: It is a heat treatment process, which improves the case depth hardness of a component by diffusing carbon into the surface layer to improve wear and fatigue resistance. The workpieces are pre-heated and then held for a period of time at an elevated temperature in the austenitic region of the specific alloy, typically between 820 and 940°C. During the thermal cycle the components are subject to an enriched carbon atmosphere such that nascent species of carbon can diffuse into the surface layers of the component. The rate of diffusion is dependent on the alloy and carbon potential of the atmosphere. Care must be taken to ensure that only sufficient carbon is available in the atmosphere at any one time to satisfy the take up rate of the alloy to accept the carbon atoms.

Pack Carburizing: It is a heat treatment process in which carbon monoxide derived from a solid compound decomposes at the metal surface into nascent carbon and carbon dioxide. The nascent carbon is absorbed into the metal, and the carbon dioxide immediately reacts with carbonaceous material present in the solid carburizing compound to produce fresh carbon monoxide. The formation of carbon monoxide is enhanced by energizers or catalysts, such as barium carbonate, calcium carbonate, potassium carbonate, and sodium carbonate that are present in the carburizing compound. These energizers facilitate the reduction of carbon dioxide with carbon to form carbon monoxide. Thus, in a closed system, the amount of energizer does not change. Carburizing continues as long as enough carbon is present to react with the excess carbon dioxide. Pack carburizing is no longer a major commercial process.


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