Steel parts may be surface hardened by heating in contact with a cyanide salt, followed by quenching. Only a thin case is obtained by this method. Cyaniding is, however, a rapid and economical method of case hardening and may be used in some instances for relatively unimportant parts. The work to be hardened is immersed in a bath of molten sodium or potassium cyanide from 30 to 60 min. The cyanide bath should be mainlined at temperature of 760–899°C. Immediately after removal from the bath, the parts are quenched in water. The case obtained in this manner is due principally to the formation of carbides and nitrides on the surface of the steel. The use of a closed pot and ventilating hood are required for cyaniding, as cyanide vapours are extremely poisonous.
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